Journal of Liaoning Petrochemical University
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Investigation on Olefin-Decrement Reaction Rule of FCC Gasoline by Catalytic Cracking
LI Wen-shen, LIU Jie
Abstract380)      PDF (305KB)(241)      
 
The effects of reaction temperature, reaction time and mass ratio of catalyst to oil on product distribution, yields of light olefins (including ethylene, propylene and butylene), and group composition of gasoline upgraded were investigated by using micro-reactor and gas chromatograph integrated method in catalytic reformulating. The experimental results show that olefin content in gasoline decreases from 42.6% in raw material to nearly 13.4%, which is met with the requirements of new gasoline standard. The contents of iso-alkane and aromatics are markedly increased from 28.4% and 18.2% to 40.4% and 35.7%, respectively, while the octane number of gasoline is not reduced. Meanwhile, higher yields of light olefins (25%) are also obtained after FCC gasoline being reformulated under laboratory conditions. In addition, higher reaction temperature, longer reaction time, and higher mass ratio of catalyst to oil are beneficial to decrease olefin content of FCC gasoline and increase the yields of light olefins.
2010, 30 (3): 13-17. DOI: 10.3696/j.issn.1672-6952.2010.03.004
Study on Petroleum Sulfonate Produced by Extract Oil of Lubricating Oil
SHEN Na, SUN Ling-ling, LIU Jie, LI Xiao-ou, LI Wen-shen
Abstract347)      PDF (249KB)(283)      
Petroleum sulfonate is obtained through sulfonate reaction using extract oil from refining VGO.no.5 in the No.1 refinery of Fushun as raw materials and oleum as sulfonation agent in this paper. And the effect of reaction conditions such as acid/oil ratio, temperature and reaction time on product yield is studied. The yield of petroleum sulfonate is 64.14% when acid/oil ratio is 0.12∶1, temperature is 60 ℃and reaction time is 45 min. After petroleum sulfonic acid is reacted with 10% sodium hydroxide, petroleum sulfonate is obtained by extraction with ethanol and its active substance content is 42.1%, which can be used as surface active reagent.
2008, 28 (2): 22-24.